МРНТИ 31.25.19

№2-2024

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https://doi.org/10.53939/1560-5655_2024_2_18

Mukhanov D.K.

Abstract. In this study, new nitrogen-rich conjugated microporous polymers were synthesized using the Buchwald-Hartwig cross-coupling reaction. The synthesized polymers were characterized using various methods, including X-ray diffraction (XRD), ultraviolet-visible-near-infrared (UV-Vis-NIR) spectroscopy, Fourier transform infrared (FT-IR) spectroscopy, Brunauer-Emmett-Teller (BET) surface area
analysis, and pore size distribution (PSD) determination using non-local density functional theory (NLDFT). The results provide important information about the structure and properties of synthesized materials, which contributes to a deeper understanding of their characteristics. The obtained characteristics of the material allow us to judge the quality and purity of the obtained polymers, which is important for further research, as well as serve as a basis for the development of new synthesis methods or improvement of existing technologies.
Key words: Conjugated microporous polymers, Buchwald-Hartwig cross-combination reaction, Porous organic materials, synthesis.

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